Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes.
نویسندگان
چکیده
The behavior of the Lewis-acid adducts of two copper-nitrene [Cu(NR)](+) complexes in nitrene-transfer and H-atom abstraction reactions have been demonstrated to depend on the nature of the nitrene substituents. Two-state reactivity, in which a singlet ground state and a nearby triplet excited-state both contribute, provides a useful model for interpreting reactivity trends of the two compounds.
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عنوان ژورنال:
- Chemical communications
دوره 50 69 شماره
صفحات -
تاریخ انتشار 2014